(a) Deconvoluted sticking function S0(Ei, ν) for D2 at Ag(111) (lines) [34] and the computed initial state resolved reaction probabilities for the (ν = 1 − 4, j = 0) states (symbols with matching color). (b) The same functions S0(Ei,ν) resulting from the experimental analyses [34] are compared with computed initial vibrational state selected reaction probab- ilities with Boltzmann averaging over the rotational states using Tn = 2012 K. Comparison between the computed initial state resolved reaction prob- abilities and initial vibrational state resolved reaction probabilities is also shown for the ν = 4 state.